box-behnken design of experiments investigation foradsorption of cd2+ onto carboxymethyl chitosan magnetic nanoparticles

نویسندگان

a igder

ali akbar rahmani

ali fazlavi

mohammad hossein ahmadi

mohammad hossein ahmadi azqhandi

چکیده

the main objective of the present study is to investigate the feasibility of using carboxymethyl chitosan magnetic nanoparticles (ccmn) for the adsorption of cd2+. the study also reports important parameters, which affect the adsorption process, i.e., ph, adsorbent dose, contact time and concentration of cd2+, using box-behnken designs. firstly, functional carboxymethyl chitosan magnetic nanoparticles (about 33 nm) was prepared by chemical coprecipitating and characterized by means of scanning electron microscope (sem), x-ray diffraction (xrd), fourier transform infrared spectroscopy (ftir). then, ccmn was used as the adsorbent for the treatment of effluent. the anova result of the full model shows that ph, adsorbent dosage and metal concentration had a significant effect on metal removal. in addition, this parameters indicates which contact time variable does not have a significant effect (p>0.05).

برای دانلود باید عضویت طلایی داشته باشید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Box-Behnken Design of Experiments Investigation forAdsorption of Cd2+ onto carboxymethyl Chitosan Magnetic Nanoparticles

The main objective of the present study is to investigate the feasibility of using Carboxymethyl chitosan magnetic nanoparticles (CCMN) for the adsorption of Cd2+. The study also reports important parameters, which affect the adsorption process, i.e., pH, adsorbent dose, contact time and concentration of Cd2+, using Box-Behnken designs. Firstly, functional carboxymethyl chitosan magnetic nanopa...

متن کامل

Mercury Removal From Aqueous Solutions With Chitosan-Coated Magnetite Nanoparticles Optimized Using the Box-Behnken Design

BACKGROUND Nowadays, removal of heavy metals from the environment is an important problem due to their toxicity. OBJECTIVES In this study, a modified method was used to synthesize chitosan-coated magnetite nanoparticles (CCMN) to be used as a low cost and nontoxic adsorbent. CCMN was then employed to remove Hg(2+) from water solutions. MATERIALS AND METHODS To remove the highest percentage ...

متن کامل

mercury removal from aqueous solutions with chitosan-coated magnetite nanoparticles optimized using the box-behnken design

background nowadays, removal of heavy metals from the environment is an important problem due to their toxicity. objectives in this study, a modified method was used to synthesize chitosan-coated magnetite nanoparticles (ccmn) to be used as a low cost and nontoxic adsorbent. ccmn was then employed to remove hg2+ from water solutions. materials and methods to remove the highest percentage of mer...

متن کامل

Synthesis and Characterization of Fe3O4 Magnetic Nanoparticles Coated with Carboxymethyl Chitosan Grafted Sodium Methacrylate

N-sodium acrylate-O-carboxymethyl chitosan [CMCH-g-PAA(Na)] bound Fe3O4 nanoparticles were developed as a novel magnetic nanoparticles with an ionic structure that can be potentially used in many fields. CMCH-g-PAA (Na) was obtained by grafting of sodium polyacrylate on O-carboxymethyl chitosan, which is an amphiphilic polyelectrolyte with the biocompatibility and biodegra...

متن کامل

synthesis and characterization of fe3o4 magnetic nanoparticles coated with carboxymethyl chitosan grafted sodium methacrylate

n-sodium acrylate-o-carboxymethyl chitosan [cmch-g-paa(na)] bound fe3o4 nanoparticles were developed as a novel magnetic nanoparticles with an ionic structure that can be potentially used in many fields. cmch-g-paa (na) was obtained by grafting of sodium polyacrylate on o-carboxymethyl chitosan, which is an amphiphilic polyelectrolyte with the biocompatibility and biodegradability properties. a...

متن کامل

Desulfurization of coal by HNO3 leaching: Optimization of influential factors using Box-Behnken design

Sulfur is one of the most significant impurities in coal, which reduces the quality of coal and also results in environmental pollution. This work was aimed to investigate the removal of sulfur from coal by the leaching method employing parameters expected to affect the removal rate such as acid concentration (10-30%), temperature (40-80 °C), and reaction time (40-100 min). A response surface m...

متن کامل

منابع من

با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید


عنوان ژورنال:
journal of mining and environment

ناشر: university of shahrood

ISSN 2251-8592

دوره 3

شماره 1 2012

میزبانی شده توسط پلتفرم ابری doprax.com

copyright © 2015-2023